Development and optimization of biomass-derived activated carbon for enhancing water retention in agriculture
DOI:
https://doi.org/10.32523/5da1jn33Keywords:
activated carbon, agricultural waste, moisture-retaining substrate, porous structure, adsorption propertiesAbstract
Sustainable agriculture amid climate change and water scarcity necessitates innovative materials with enhanced water-holding capacity, such as biomass-based carbon substrates. This study investigates the textural and adsorption characteristics of activated carbon (AC) synthesized from rice husk using varying mass ratios of sorbent to potassium hydroxide (KOH) (1:1, 1:2, 1:3, and 1:4). The objective was to optimize chemical activation conditions to develop a porous structure for efficient water retention. The methodology employed density functional theory (DFT) and the Barrett–Joyner–Halenda (BJH) method for structural analysis. Results indicated that a 1:3 ratio achieves the maximum total pore volume (1.6 cm3/g) and a high specific surface area (2900 m2/g). Fourier-transform infrared spectroscopy (FTIR) confirmed hydrophilic functional groups (O-H, C=O, C-O) essential for moisture binding. Water retention experiments, conducted in triplicate (n=3), demonstrated that the 1:3 sample maintains superior moisture stability at both 22°C and 50°C compared to low-activation (1:1, 1:2) and over-activated (1:4) samples. Comparative analysis reveals that the optimized AC outperforms traditional biochar and zeolites in specific surface area while ensuring the long-term stability of the carbon framework. These findings confirm the critical role of balanced micro- and mesoporosity in slowing water evaporation. The study suggests that such materials are promising, environmentally friendly, moisture-conserving agents for increasing agrocenose productivity in arid regions.
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Copyright (c) 2026 Ерлан Досжанов, Дана Ахметжанова, Арман Жумажанов, Оспан Досжанов, Зере Нұрбол, Мағжан Оспан (Автор)

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